The discovery was made by Stanford graduate student Ming Gong, co-lead author of the study. "Ming discovered a nickel-metal/nickel-oxide structure that turns out to be more active than pure nickel metal or pure nickel oxide alone," Dai said. "This novel structure favors hydrogen electrocatalysis, but we still don't fully understand the science behind it."
The nickel/nickel-oxide catalyst significantly lowers the voltage required to split water, which could eventually save hydrogen producers billions of dollars in electricity costs, according to Gong. His next goal is to improve the durability of the device.
"The electrodes are fairly stable, but they do slowly decay over time," he said. "The current device would probably run for days, but weeks or months would be preferable. That goal is achievable based on my most recent results"
The researchers also plan to develop a water splitter than runs on electricity produced by solar energy.
"Hydrogen is an ideal fuel for powering vehicles, buildings and storing renewable energy on the grid," said Dai. "We're very glad that we were able to make a catalyst that's very active and low cost. This shows that through nanoscale engineering of materials we can really make a difference in how we make fuels and consume energy."
Other authors of the study are Wu Zhou, Oak Ridge National Laboratory (co-lead author); Mingyun Guan, Meng-Chang Lin, Bo Zhang, Di-Yan Wang and Jiang Yang, Stanford; Mon-Che Tsai and Bing-Joe Wang, National Taiwan University of Science and Technology; Jiang Zhou and Yongfeng Hu, Canadian Light Source Inc.; and Stephen J. Pennycook, University of Tennessee.
Principal funding was provided by the Global Climate and Energy Project (GCEP) and the Precourt Institute for Energy at Stanford and by the U.S. Department of Energy.
Mark Shwartz writes about energy technology at the Precourt Institute for Energy at Stanford University.
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